Title: The viscosity of dilute water vapor revisited: New reference values from experiment and theory for temperatures between (250 and 2500) K
Authors: Hellmann, Robert 
Vogel, Eckhard
Language: eng
Issue Date: 10-Dec-2015
Document Type: Article
Journal / Series / Working Paper (HSU): Journal of chemical & engineering data
Volume: 60
Issue: 12
Page Start: 3600
Page End: 3605
Abstract: 
Previously reported as well as unpublished experimental data for the viscosity of dilute water vapor in the temperature range from (297 to 528) K, which were obtained using an oscillating-disk viscometer, have been re-evaluated and extrapolated to the limit of zero density. The relative combined expanded (k = 2) uncertainty of the re-evaluated data is 0.2 % at room temperature (297 K to 302 K), 0.4 % at higher temperatures up to 450 K, and 1.0 % at temperatures above 450 K. The classical kinetic theory of molecular gases has been applied to compute the viscosity in the limit of zero density for temperatures between (250 and 2500) K using a highly accurate ab initio potential for the H₂O molecule pair. In the temperature range from (311 to 438) K, the experimental zero-density data differ by only about +0.1 % from the calculated values. A new correlation for the zero-density limit, based on both the experimental data and the theoretically calculated values, is proposed. The relative combined expanded (k = 2) uncertainty of the correlation is estimated to be 0.4 % between (300 and 500) K, increasing to 0.8 % at 250 K and 2.0 % at 2500 K. The new correlation represents a significant improvement over the current IAPWS zero-density correlation.
Organization Units (connected with the publication): Universität Rostock
ISSN: 0021-9568
1520-5134
Publisher DOI: 10.1021/acs.jced.5b00599
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