Title: | The viscosity of dilute water vapor revisited: New reference values from experiment and theory for temperatures between (250 and 2500) K | Authors: | Hellmann, Robert Vogel, Eckhard |
Language: | eng | Issue Date: | 10-Dec-2015 | Document Type: | Article | Journal / Series / Working Paper (HSU): | Journal of chemical & engineering data | Volume: | 60 | Issue: | 12 | Page Start: | 3600 | Page End: | 3605 | Abstract: | Previously reported as well as unpublished experimental data for the viscosity of dilute water vapor in the temperature range from (297 to 528) K, which were obtained using an oscillating-disk viscometer, have been re-evaluated and extrapolated to the limit of zero density. The relative combined expanded (k = 2) uncertainty of the re-evaluated data is 0.2 % at room temperature (297 K to 302 K), 0.4 % at higher temperatures up to 450 K, and 1.0 % at temperatures above 450 K. The classical kinetic theory of molecular gases has been applied to compute the viscosity in the limit of zero density for temperatures between (250 and 2500) K using a highly accurate ab initio potential for the H₂O molecule pair. In the temperature range from (311 to 438) K, the experimental zero-density data differ by only about +0.1 % from the calculated values. A new correlation for the zero-density limit, based on both the experimental data and the theoretically calculated values, is proposed. The relative combined expanded (k = 2) uncertainty of the correlation is estimated to be 0.4 % between (300 and 500) K, increasing to 0.8 % at 250 K and 2.0 % at 2500 K. The new correlation represents a significant improvement over the current IAPWS zero-density correlation. |
Organization Units (connected with the publication): | Universität Rostock | ISSN: | 00219568 | Publisher DOI: | 10.1021/acs.jced.5b00599 |
Appears in Collections: | 6 - Bibliographic Data - Publications of the HSU Researchers (before HSU) |
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