Single- and double-periodic one-dimensional photonic lattices are formed in lithium niobate using both titanium in-diffusion and holographic grating recording. We investigate linear band structures and diffraction properties of such superlattices and observe a decrease of discrete diffraction with increasing modulation depth of the second superimposed lattice. In weakly modulated superlattices with tailored diffraction properties, our results demonstrate the formation of discrete solitons having a propagation constant inside the extra mini-gap formed inside the Brillouin zone. © 2007 Springer-Verlag.