Correlating the 3D morphology of polymer-based battery electrodes with effective transport properties

Prifling, Benedikt; Fuchs, Lukas; Yessim, Aigerim; Osenberg, Markus; Paulisch, Melanie; Zimmer, Philip; Hager, Martin D.; Schubert, Ulrich S.; Manke, Ingo; Carraro, Thomas; Schmidt, Volker

doi:10.1021/acsami.4c17522

Correlating the 3D morphology of polymer-based battery electrodes with effective transport properties

Publication date

2024-11-21

Document type

Forschungsartikel

Author

Prifling, Benedikt

Fuchs, Lukas

Yessim, Aigerim

Osenberg, Markus

Paulisch, Melanie

Zimmer, Philip

Hager, Martin D.

Schubert, Ulrich S.

Manke, Ingo

Carraro, Thomas

Schmidt, Volker

Organisational unit

Angewandte Mathematik

DTEC.bw

DOI

10.1021/acsami.4c17522

URI

https://openhsu.ub.hsu-hh.de/handle/10.24405/22942

Publisher

American Chemical Society (ACS)

Series or journal

ACS Applied Materials & Interfaces

ISSN

1944-8244

Periodical volume

16

Periodical issue

48

First page

66571

Last page

66583

Part of the university bibliography

✅

Language

English

Keyword

dtec.bw

Abstract

Polymer-based batteries represent a promising candidate for next-generation batteries due to their high power densities, decent cyclability, and environmentally friendly synthesis. However, their performance essentially depends on the complex multiscale morphology of their electrodes, which can significantly affect the transport of ions and electrons within the electrode structure. In this paper, we present a comprehensive investigation of the complex relationship between the three-dimensional (3D) morphology of polymer-based battery electrodes and their effective transport properties. In particular, focused ion beam scanning electron microscopy (FIB-SEM) is used to characterize the 3D morphology of three polymer-based electrodes which differ in material composition. The subsequent segmentation of FIB-SEM image data into active material, carbon-binder domain and pore space enables a comprehensive statistical analysis of the electrode structure and a quantitative morphological comparison of the electrode samples. Moreover, spatially resolved numerical simulations allow for computing effective properties of ionic and electronic transport. The obtained results are used for establishing analytical regression formulas which describe quantitative relationships between the 3D morphology of the electrodes and their effective transport properties. To the best of our knowledge, this is the first time that the 3D structure of polymer-based battery electrodes is quantitatively investigated at the nanometer scale.

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This publication is licensed under CC-BY 4.0 (https://creativecommons.org/licenses/by/4.0/).

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